European Union Pension Directive

[Excerpt] This Directive thus represents a first step on the way to an internal market for occupational retirement provision organised on a European scale. By setting the ‘prudent person’ rule as the underlying principle for capital investment and making it possible for institutions to operate across borders, the redirection of savings into the sector of occupational retirement provision is encouraged, thus contributing to economic and social progress. The prudential rules laid down in this Directive are intended both to guarantee a high degree of security for future pensioners through the imposition of stringent supervisory standards, and to clear the way for the efficient management of occupational pension schemes

Field-portable-XRF reveals the ubiquity of antimony in plastic consumer products.

Very little systematic information exists on the occurrence and concentrations of antimony (Sb) in consumer products. In this study, a Niton XL3t field-portable-X-ray fluorescence (FP-XRF) spectrometer was deployed in situ and in the laboratory to provide quantitative information on Sb dissipated in plastic items and fixtures (including rubber, textile and foamed materials) from the domestic, school, vehicular and office settings. The metalloid was detected in 18% of over 800 measurements performed, with concentrations ranging from about 60 to 60,000μgg(-1). The highest concentrations were encountered in white, electronic casings and in association with similar concentrations of Br, consistent with the use of antimony oxides (e.g. Sb2O3) as synergistic flame retardants. Concentrations above 1000μgg(-1), and with or without Br, were also encountered in paints, piping and hosing, adhesives, whiteboards, Christmas decorations, Lego blocks, document carriers, garden furniture, upholstered products and interior panels of private motor vehicles. Lower concentrations of Sb were encountered in a wide variety of items but its presence (without Br) in food tray packaging, single-use drinks bottles, straws and small toys were of greatest concern from a human health perspective. While the latter observations are consistent with the use of antimony compounds as catalysts in the production of polyethylene terephthalate, co-association of Sb and Br in many products not requiring flame retardancy suggests that electronic casings are widely recycled. Further research is required into the mobility of Sb when dissipated in new, recycled and aged polymeric materials

Frequency-dependence of large-signal properties in lead-free piezoceramics

The dependence of large signal properties of (1-x)(0.81Bi 1/2Na 1/2TiO 3-0.19Bi 1/2K 1/2TiO 3)-xBi(Zn 1/2Ti 1/2)O 3 with x 0.02, 0.03, and 0.04 on the measurement frequency was investigated for a wide range of frequencies from 0.1 Hz to 100 Hz. A significant frequency dispersion in the characteristic parameters representatively maximum and coercive values was denoted. On extension with the temperature dependent dielectric permittivity measurement, it was shown that the observed frequency dependence is primarily correlated with the dynamics of field-induced phase transition from a relaxor state to a long-range ferroelectric state. Increasing the substitutional disorder introduced by Bi(Zn 1/2Ti 1/2)O 3 addition was demonstrated to pronounce the frequency dependence. It was proposed that the change be due to the increase in random fields and consequent dominance of ergodicity, based on the frequency-dependent hysteresis measurements at an elevated temperature above so-called induced-ferroelectric-to-relaxor transition temperature.open8

Securing effective and equitable coverage of marine protected areas : the UK's progress towards achieving Convention on Biological Diversity commitments and lessons learned for the way forward

Current international agreements call for protecting 10% of marine and coastal waters by 2020, with the intention of increasing that target to 30% by 2030. With 24% of its territorial waters protected, the UK falls short of the new expected target. As well as quantitative targets, qualitative criteria have been internationally agreed for protected area designation, including minimum coverage values and characteristics that encompass effectively and equitably managed, ecologically representative and well-connected systems of protected areas and other effective area-based conservation measures, and integrated into the wider landscape and seascape. The legal framework supporting protected area designations at sea is summarized and explained for UK territorial waters. Efforts to date to achieve current marine protected area (MPA) targets are reviewed, with emphasis on how well the existing protected area portfolio captures the qualitative criteria. Examples are given of other effective conservation measures complementary to formalized MPAs, especially with regard to achieving and promoting qualitative criteria for biodiversity conservation, including appropriate recognition of and support for areas conserved by indigenous people, local communities and private entities. A precis on the governance of MPAs and other effective conservation measures in the UK and its overseas territories is presented. Whilst the UK has made exceptional progress with quantitative MPA coverage, it is still not clear whether designated areas offer effective protection. A UK-level strategy is in place to address this; and at site level, Lyme Bay MPA illustrates the benefits of addressing qualitative criteria. Illustrated by the UK example, an urgent call is made for ongoing and future marine in situ area-based conservation efforts to substantiate quantitative and qualitative considerations, and to ensure that MPA networks are ultimately fit for purpose

Concentrations and Migratabilities of Hazardous Elements in Second-Hand Children's Plastic toys.

About 200 second-hand plastic toys sourced in the UK have been analyzed by X-ray fluorescence spectrometry for hazardous elements (As, Ba, Cd, Cr, Hg, Pb, Sb, Se) and Br as a proxy for brominated flame retardants. Each element was detected in >20 toys or components thereof with the exception of As, Hg, and Se, with the frequent occurrence of Br, Cd, and Pb and at maximum concentrations of about 16000, 20000, and 5000 μg g-1, respectively, of greatest concern from a potential exposure perspective. Migration was evaluated on components of 26 toys under simulated stomach conditions (0.07 M HCl) with subsequent analysis by inductively coupled plasma spectrometry. In eight cases, Cd or Pb exceeded their migration limits as stipulated by the current EU Toy Safety Directive (17 and 23 μg g-1, respectively), with Cd released from yellow and red Lego bricks exceeding its limit by 1 order of magnitude. Two further cases were potentially noncompliant based on migratable Cr, with one item also containing >250 μg g-1migratable Br. While there is no retroactive regulation on second-hand toys, consumers should be aware that old, mouthable, plastic items may present a source of hazardous element exposure to infants

Beyond the Front Page: Measuring Third Party Dynamics in the Field

In the modern Web, service providers often rely heavily on third parties to run their services. For example, they make use of ad networks to finance their services, externally hosted libraries to develop features quickly, and analytics providers to gain insights into visitor behavior. For security and privacy, website owners need to be aware of the content they provide their users. However, in reality, they often do not know which third parties are embedded, for example, when these third parties request additional content as it is common in real-time ad auctions. In this paper, we present a large-scale measurement study to analyze the magnitude of these new challenges. To better reflect the connectedness of third parties, we measured their relations in a model we call third party trees, which reflects an approximation of the loading dependencies of all third parties embedded into a given website. Using this concept, we show that including a single third party can lead to subsequent requests from up to eight additional services. Furthermore, our findings indicate that the third parties embedded on a page load are not always deterministic, as 50% of the branches in the third party trees change between repeated visits. In addition, we found that 93% of the analyzed websites embedded third parties that are located in regions that might not be in line with the current legal framework. Our study also replicates previous work that mostly focused on landing pages of websites. We show that this method is only able to measure a lower bound as subsites show a significant increase of privacy-invasive techniques. For example, our results show an increase of used cookies by about 36% when crawling websites more deeply

The rise and change of the competence strategy: reflections on twenty-five years of skills policies in the EU

The principal aim of this article is to provide a historical overview of 25 years of competence policy in the European Union, highlighting connections between past and current initiatives and outlining possible scenarios for the decade to come. The article presents the social investment turn in social policy as the critical political background against which the emergence of a competence strategy in European Union education policy should be analysed and understood. The competence strategy, it is argued, finds its roots in a renewed attention at the European Union level for harmonising educational outputs and labour market demands. While trying to produce a schematic history of the emergence and change of the competence strategy, the article does not seek to offer strict definitions of competence itself; instead, it conveys the nebulous and context-dependent nature of the concept

Analysis of trends in mapping and assessment of ecosystem condition in Europe

Ecosystem condition is the overall quality of an ecosystem unit, in terms of its biological, physical and chemical characteristics underpinning its capacity to generate ecosystem services. Changes in ecosystem condition affect the delivery of services and therefore human well-being. Despite increasing research in this field, the relations between biodiversity, ecosystem condition and services are still not well understood. This study examined scientific articles and reports to analyse the development of ecosystem condition mapping and assessments in Europe since the year 2000. The aim was to provide an overview of the current state of research and to highlight some challenges for ecosystem condition and ecosystem services research. The review analysed the ecosystems under study, scales, methods, indicators, and the ecosystem services assessed. Based on this review, some gaps were identified, especially in the methods used for condition assessment, the coverage of ecosystems, and the applicability of indicators in policy. It is necessary to develop integrative methods to determine ecosystems condition and its influence on the ecosystem service provision, in order to produce robust information. The results of this review can be harnessed by people who need an overview about existing ecosystem condition studies, such as scientists, land managers or decision makers

Application of a zero-dimensional model to assess the effect of swirl on indicated efficiency

This is the author s version of a work that was accepted for publication in International Journal of Engine Research. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published as https://doi.org/10.1177/1468087418779726[EN] Increasing internal combustion engine efficiency continues being one of the main goals of engine research. To achieve this objective, different engine strategies are being developed continuously. However, the assessment of these techniques is not straightforward due to their influence on various intermediate phenomena inherent to the combustion process, which finally result in indicated efficiency trade-offs. During this work, a new methodology to assess these intermediate imperfections on gross indicated efficiency using a zero-dimensional model is developed. This methodology is applied to a swirl parametric study, where it has been concluded that the heat transfer and the rate of heat release are the single relevant changing phenomena. Results show that heat transfer always increases with swirl affecting negatively gross indicated efficiency (around -0.5%), while the impact of combustion velocity is not monotonous. It is enhanced up to a certain swirl ratio (it changes with engine speed) at low engine speed (resulting in an increment of +1.7% in gross indicated efficiency), but it is slowed down at high engine speed with the consequent worsening of gross indicated efficiency (-0.8%).The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was partially funded by GM Global R&D and the Government of Spain through Project TRA2013-41348-R. D. B.-C. was partially supported through contract FPI-S2-2016-1356 of the Programa de Apoyo para la Investigacion y Desarrollo (PAID) of Universitat Politecnica de Valencia.Broatch, A.; Martín, J.; García Martínez, A.; Blanco-Cavero, D.; Warey, A.; Domenech, V. (2019). Application of a zero-dimensional model to assess the effect of swirl on indicated efficiency. International Journal of Engine Research. 20(8-9):837-848. https://doi.org/10.1177/1468087418779726S837848208-9Mohan, B., Yang, W., & Chou, S. kiang. (2013). Fuel injection strategies for performance improvement and emissions reduction in compression ignition engines—A review. Renewable and Sustainable Energy Reviews, 28, 664-676. doi:10.1016/j.rser.2013.08.051Agarwal, A. K., Srivastava, D. K., Dhar, A., Maurya, R. K., Shukla, P. C., & Singh, A. P. (2013). Effect of fuel injection timing and pressure on combustion, emissions and performance characteristics of a single cylinder diesel engine. Fuel, 111, 374-383. doi:10.1016/j.fuel.2013.03.016Hiwase, S. D., Moorthy, S., Prasad, H., Dumpa, M., & Metkar, R. M. (2013). Multidimensional Modeling of Direct Injection Diesel Engine with Split Multiple Stage Fuel Injections. Procedia Engineering, 51, 670-675. doi:10.1016/j.proeng.2013.01.095Canakci, M. (2012). Combustion characteristics of a DI-HCCI gasoline engine running at different boost pressures. Fuel, 96, 546-555. doi:10.1016/j.fuel.2012.01.042Pan, M., Shu, G., Wei, H., Zhu, T., Liang, Y., & Liu, C. (2014). Effects of EGR, compression ratio and boost pressure on cyclic variation of PFI gasoline engine at WOT operation. Applied Thermal Engineering, 64(1-2), 491-498. doi:10.1016/j.applthermaleng.2013.11.013Fontana, G., & Galloni, E. (2010). Experimental analysis of a spark-ignition engine using exhaust gas recycle at WOT operation. Applied Energy, 87(7), 2187-2193. doi:10.1016/j.apenergy.2009.11.022Verhelst, S., Demuynck, J., Sierens, R., & Huyskens, P. (2010). Impact of variable valve timing on power, emissions and backfire of a bi-fuel hydrogen/gasoline engine. International Journal of Hydrogen Energy, 35(9), 4399-4408. doi:10.1016/j.ijhydene.2010.02.022Fontana, G., & Galloni, E. (2009). Variable valve timing for fuel economy improvement in a small spark-ignition engine. Applied Energy, 86(1), 96-105. doi:10.1016/j.apenergy.2008.04.009Perini, F., Miles, P. C., & Reitz, R. D. (2014). A comprehensive modeling study of in-cylinder fluid flows in a high-swirl, light-duty optical diesel engine. Computers & Fluids, 105, 113-124. doi:10.1016/j.compfluid.2014.09.011Wei, S., Wang, F., Leng, X., Liu, X., & Ji, K. (2013). Numerical analysis on the effect of swirl ratios on swirl chamber combustion system of DI diesel engines. Energy Conversion and Management, 75, 184-190. doi:10.1016/j.enconman.2013.05.044Olmeda, P., Martín, J., Blanco-Cavero, D., Warey, A., & Domenech, V. (2017). Effect of in-cylinder swirl on engine efficiency and heat rejection in a light-duty diesel engine. International Journal of Engine Research, 18(1-2), 81-92. doi:10.1177/1468087417693078Sandalcı, T., & Karagöz, Y. (2014). Experimental investigation of the combustion characteristics, emissions and performance of hydrogen port fuel injection in a diesel engine. International Journal of Hydrogen Energy, 39(32), 18480-18489. doi:10.1016/j.ijhydene.2014.09.044Sorate, K. A., & Bhale, P. V. (2015). Biodiesel properties and automotive system compatibility issues. Renewable and Sustainable Energy Reviews, 41, 777-798. doi:10.1016/j.rser.2014.08.079Ryan, T. W., & Callahan, T. J. (1996). Homogeneous Charge Compression Ignition of Diesel Fuel. SAE Technical Paper Series. doi:10.4271/961160Kiplimo, R., Tomita, E., Kawahara, N., & Yokobe, S. (2012). Effects of spray impingement, injection parameters, and EGR on the combustion and emission characteristics of a PCCI diesel engine. Applied Thermal Engineering, 37, 165-175. doi:10.1016/j.applthermaleng.2011.11.011Ramesh, A. K., Shaver, G. M., Allen, C. M., Nayyar, S., Gosala, D. B., Caicedo Parra, D., … Nielsen, D. (2017). Utilizing low airflow strategies, including cylinder deactivation, to improve fuel efficiency and aftertreatment thermal management. International Journal of Engine Research, 18(10), 1005-1016. doi:10.1177/1468087417695897Shelby, M. H., Leone, T. G., Byrd, K. D., & Wong, F. K. (2017). Fuel Economy Potential of Variable Compression Ratio for Light Duty Vehicles. SAE International Journal of Engines, 10(3), 817-831. doi:10.4271/2017-01-0639Yamasaki, Y., Ikemura, R., & Kaneko, S. (2017). Model-based control of diesel engines with multiple fuel injections. International Journal of Engine Research, 19(2), 257-265. doi:10.1177/1468087417747738Weberbauer, F., Rauscher, M., Kulzer, A., Knopf, M., & Bargende, M. (2005). Generally applicate split of losses for new combustion concepts. MTZ worldwide, 66(2), 17-19. doi:10.1007/bf03227736Payri, F., Olmeda, P., Guardiola, C., & Martín, J. (2011). Adaptive determination of cut-off frequencies for filtering the in-cylinder pressure in diesel engines combustion analysis. Applied Thermal Engineering, 31(14-15), 2869-2876. doi:10.1016/j.applthermaleng.2011.05.012Lapuerta, M., Armas, O., & Hernández, J. J. (1999). Diagnosis of DI Diesel combustion from in-cylinder pressure signal by estimation of mean thermodynamic properties of the gas. Applied Thermal Engineering, 19(5), 513-529. doi:10.1016/s1359-4311(98)00075-1Payri, F., Molina, S., Martín, J., & Armas, O. (2006). Influence of measurement errors and estimated parameters on combustion diagnosis. Applied Thermal Engineering, 26(2-3), 226-236. doi:10.1016/j.applthermaleng.2005.05.006Torregrosa, A. J., Olmeda, P., Martín, J., & Romero, C. (2011). A Tool for Predicting the Thermal Performance of a Diesel Engine. Heat Transfer Engineering, 32(10), 891-904. doi:10.1080/01457632.2011.54863